Reactions of Decomposition and Oxidation of Aliphatic Nitrocompounds in Supercritical Water
نویسندگان
چکیده
The kinetics of nitromethane, nitroethane and 1-nitropropane decomposition and oxidation in supercritical water near the critical point has been studied in a flow reactor. The reaction rate constants have been calculated on the assumption of the first order reaction. The pressure varied over a wide range produced strong effect on the rate of the nitrocompounds decomposition in supercritical water. The rate of aliphatic nitrocompounds oxidation in supercritical water increased with increasing number of carbon atoms.
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